The phrase 盛开 means to bloom, as in, "池塘里的荷花盛开." Is this pronounced as "shèng kāi", or is it pronounced as "chéng kāi"?
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In this case, you pronounce it as "shèng kāi." The other pronunciation, "chéng" is for the phrase "盛饭."
You can guess the pronunciation according to its usage:
by the way, 盛"shèng" is also used as a surname, such as this man