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In what situations would you use one of the following instead of the others?

男女 nán nǚ

公母 gōng mǔ

雄雌 xióng cí

Is it a matter of formality or is each term confined to a particular field (e.g. biology)?

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We have another pair called 公母. – fefe Jan 9 '12 at 14:16
Thanks fefe, I have edited the question to include that pair. – Bjorn Jan 9 '12 at 14:28

2 Answers

up vote 5 down vote accepted

男女 is used only for humans.

公母 is normally used on animals.

雄雌 is more academic.

公母 is usually used with terms closer to everyday life:

公鸡 / 母鸡 gōngjī / mǔjī for cock / hen

For biological terminology, usually 雄 / 雌 would be used:

雄蕊 / 雌蕊 xióngruǐ / cīruǐ for stamen / carpel

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Usually 男女 is used when we are talking about people. 公母 or 雄雌 is used when we are talking about animals.

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