Think about it like in English.
The original sentence you gave was 我在十一点半给你打电话,好吗?(好的sounds weird,say 好吗)
将 means I'm going to; so adding it becomes:
"I'm going to call you at 11:30, alright?" 我将在十一点半给你打电话, 好吗?
会 means I will; so adding it becomes: "I will call you at 11:30 alright?" 我会在十一点半给你打电话,好吗?
Now, you see the pattern right? Both indicate some time in which we would call the person. You can't randomly add verbs there, like run or jump; I run call you? Doesn't sound right, right?
On a side note, words like 立马,立即,赶紧 can also be added (indicating some kind of time, but because of the immediate urgency, adds a tone to the sentence); for instance, 赶紧在十一点半给我打电话,Call me at 11:30!(with some sentiment of anger within)